Application of 41203-22-9, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.41203-22-9, Name is 1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane, molecular formula is C14H32N4. In a Review£¬once mentioned of 41203-22-9
High-valent nonheme iron-oxo complexes: Synthesis, structure, and spectroscopy
High-valent iron-oxo intermediates have often been implicated, and in some cases identified, as the active oxidant in oxygen activating nonheme iron enzymes. Recent synthetic efforts have yielded pivotal insights into the generation of oxoiron(IV and V) complexes, and allowed thorough investigation of their spectroscopic, structural, and electronic properties. Furthermore, insight into the mechanisms by which nonheme iron sites activate dioxygen to yield high valent iron-oxo intermediates has been obtained. This review covers the great successes in iron-oxo chemistry over the past decade, detailing various efforts to obtain iron-oxo complexes in high yield, and to delve into their diverse structural and spectroscopic properties.
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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI