Related Products of 3030-47-5, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.3030-47-5, Name is N1-(2-(Dimethylamino)ethyl)-N1,N2,N2-trimethylethane-1,2-diamine, molecular formula is C9H23N3. In a Article，once mentioned of 3030-47-5
Selective cleavage of a silicon?carbon bond in tetraorganosilanes is still a great challenge. A new type of Si?C(sp3) bond cleavage in bench-stable (aminomethyl)silanes with common organolithium reagents as nucleophiles has now been identified. Suitable leaving groups are benzyl, allyl, and phenylthiomethyl groups. A beta-donor function and polar solvents are essential for the reaction. Simple switching between alpha-deprotonation and substitution is possible through slight modifications of the reaction conditions. The stereochemical course of the reaction was elucidated by using a silicon-chiral benzylsilane. The new transformation proceeds stereospecifically with inversion of configuration and can be used for the targeted synthesis of enantiomerically pure tetraorganosilanes, which are otherwise difficult to access. Quantum chemical calculations provided insight into the mechanism of the new substitution.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 3030-47-5
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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI