The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: 4-(p-Tolyl)-2,2:6,2-terpyridine( cas:89972-77-0 ) is researched.Application In Synthesis of 4-(p-Tolyl)-2,2:6,2-terpyridine.Saghatforoush, Lotf Ali; Telfer, Shane G.; Chalabian, Firoozeh; Mehdizadeh, Robabeh; Golbedaghi, Reza; Shahverdizadeh, Gholam Hossein published the article 《Cadmium(II) complexes of 4′-tolyl-2,2′:6′,2”-terpyridine: synthesis, structures, and antibacterial activities》 about this compound( cas:89972-77-0 ) in Journal of Coordination Chemistry. Keywords: cadmium terpyridine complex preparation crystal structure antibacterial activity. Let’s learn more about this compound (cas:89972-77-0).
A straightforward synthetic method was developed to prepare cadmium(II) complexes of 4′-tolyl-2,2′:6′,2”-terpyridine (ttpy) in good yields. These complexes are {[Cd(ttpy)(NO3)2][Cd2(ttpy)2(NO3)4]} (1), [Cd2(ttpy)2(N3)4]0.5CH3OH·0.125H2O (2), and {[Cd(ttpy)(SCN)(CH3COO)][Cd(ttpy)(SCN)2]2} (3). Intermol., intramol., hydrogen bonding and π-π stacking interactions were observed in the complexes, and are responsible for the arrangement of complexes in the crystal packing and play essential roles in forming different frameworks of 1-3. The antibacterial activities of the synthesized complexes were tested against three gram pos. bacteria and three gram neg. bacteria.
《Cadmium(II) complexes of 4′-tolyl-2,2′:6′,2”-terpyridine: synthesis, structures, and antibacterial activities》 provides a strategy for the preparation of materials with excellent comprehensive properties, which is conducive to broaden the application field of this compound(4-(p-Tolyl)-2,2:6,2-terpyridine)Application In Synthesis of 4-(p-Tolyl)-2,2:6,2-terpyridine.
Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI