Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.HPLC of Formula: C11H12N2O2, you can also check out more blogs about153-94-6
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The synthesis of the tetracyclic ketone <(-)-1b> was carried out in enantiospecific fashion (>98percent ee) via the 1,3-transfer of chirality from Na-methyl, Nb-benzyl tryptophan methyl ester <(+)-14> to the trans diastereomer <(-)-4b> in the Pictet-Spengler reaction.Although the condensation of 14 with aldehyde (15) in refluxing benzene generated the tetrahydro beta-carbolines (4b/5b) in a kinetic ratio (72:28), epimerization (C-1) of the cis diastereomer <(+)-5b> into the trans isomer <(-)-4b> occurred stereospecifically under acidic conditions.Dieckmann cyclizatin of either the Na-methyl, Nb-benzyl-cis-(+)-5b or trans-(-)-4b diastereomer provided the cis-bicyclo<3.3.1>-azanonane system at approximately the same rate, although the beta-keto esters were antipodal, in contrast to results reported in the Na-benzyl series by Magnus.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.HPLC of Formula: C11H12N2O2, you can also check out more blogs about153-94-6
Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI