In an article, author is Wang Jinyu, once mentioned the application of 6291-84-5, Product Details of 6291-84-5, Name is N-Methylpropane-1,3-diamine, molecular formula is C4H12N2, molecular weight is 88.15, MDL number is MFCD00008209, category is catalyst-ligand. Now introduce a scientific discovery about this category.
Synthesis of Aminophosphine Ruthenium Carbene Complex and Its Application in Olefins Metathesis Reaction
A series of Grubbs ruthenium carbene catalysts featuring an aminophosphine ligand [RuCl2 center dot (H(2)IMes) ((RHNPR22)-H-1)(=CHPh)] was synthesized and characterized by means of nuclear magnetic resonance spectrometry and single crystal X-ray diffraction. Under the ambient conditions, these ruthenium complexes were tested as catalyst for the ring-closing metathesis (RCM) reaction of N, N-diallyl-p-toluenesulfonamide, and complex G2-1 was found to have the best catalytic activity. With the catalyst loading in the range of 0.1%-2.0% (molar fraction) , G2-1 was compatible with the RCM reaction of various diene and polyene, and had high catalytic activity (>95% yield of product). G2-1 could also be used as catalyst for cross metathesis (CM) reaction of different terminal olefin substrates, up to 92% yield was achieved in the CM reaction of styrene and 3-phenoxypropene.
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Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI