Application of 18531-94-7, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 18531-94-7, Name is (R)-[1,1′-Binaphthalene]-2,2′-diol, molecular formula is C20H14O2. In a Article，once mentioned of 18531-94-7
The newly introduced tittle compounds were found to be efficient chiral auxiliaries for the asymmetric Simmons-Smith cyclopropanation of allylic alcohols and for asymmetric addition of diethylzinc to aldehydes. For example, Simmons- Smith cyclopropanation of cinnamyl alcohol in the presence of N,N,N?,N?-tetraethyl-2,2?-dihydroxy-1, 1?-binaphthyl-3, 3?-dicarboxamide (1b) proceeded with high enantioselectivity of 94% ee and addition of diethylzinc to benzaldehyde in the presence of N,N,N?,N?-tetraisopropyl-2,2?-dihydroxy-1,1?-binaphthyl- 3,3?-dicarboxamide (1e) proceeded with enantioselectivity of 99% ee. Although the reaction mechanism of these reactions is still nuclear, a monomeric seven-membered 2,2?-dihydroxy-1,1?-binaphthyl-3,3?-dicarboxamide (1)-Zn complex is considered to be an active species which catalyzes the above reactions, on the basis of NMR experiments.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Application of 18531-94-7, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 18531-94-7, in my other articles.
Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI