Sidhu, Baldeep K.; Braun, Jason D.; Herbert, David E. published an article in 2021. The article was titled 《P-C Bond Activation and Transfer of a Diphenylphosphino Unit from 1,1′-Bis(diphenylphosphino)ferrocene: Unexpected Templated Synthesis of an Ncrf N-crf P Pincer Ligand Palladium Complex》, and you may find the article in Organometallics.Name: Tris(dibenzylideneacetone)dipalladium(0) The information in the text is summarized as follows:
The Pd-catalyzed Buchwald-Hartwig amination of 2-bromo-1-iodobenzene with (4-amino-2-tert-butyl)phenanthridine using 1,1′-bis(diphenylphosphino)ferrocene (dppf) results in a side reaction involving the first reported example of P-C bond activation of dppf and the templated formation of an NΛN-ΛP-supported Pd(II) coordination complex. The full characterization of this complex along with a proposed mechanism for a rare example of unstrained P-C(cyclopentadienyl) bond activation are described. The experimental process involved the reaction of Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3Name: Tris(dibenzylideneacetone)dipalladium(0))
Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3) is used in the preparation of semiconducting polymers processed from nonchlorinated solvents into high performance thin film transistors.Name: Tris(dibenzylideneacetone)dipalladium(0)It is used as catalyst for the synthesis of epoxides, alpha-arylation of ketones, in combination with BINAP for the asymmetric heck arylation of olefins, site-selective benzylic sp3 palladium-catalyzed direct arylation and homoallylic diamination of terminal olefins.
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI