1662-01-7, 4,7-Diphenyl-1,10-phenanthroline is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
To a solution of [Pt2Me4(mu-SMe2)2] (51mg, 0.09mmol) in acetone (5mL) was added a solution of bphen (59mg, 0.18mmol) in acetone (30mL). The reaction color changed to deep red and the solution stirred for 2h at room temperature. After removal of the solvent under reduced pressure, the dark red complex was obtained and air dried. Yield: 72%; m.p. 221C (dec). Anal. Calc. for C26H22N2Pt: C, 56.01; H, 3.98; N, 5.02. Found: C, 55.67; H, 4.27; N, 4.77%. NMR data in CDCl3: delta(1H) 1.30 [s, 6H, 2J(Pt-H)=85.3Hz, Pt-Me], 7.56 [s, 10H, Ph groups], 7.75 [d, 2H, 3J(HH)=5.1Hz, H3], 7.94 [s, 2H, H5], 9.56 [d, 2H, 3J(HH)=5.1Hz, 3J(Pt-H)=25.4Hz, H2]; delta(13C)-17.1 [s, 1J(Pt-C)=804Hz, Pt-Me], 125.2 (C5), 126.1 [C3, 2J(Pt-C)=19Hz], 128.8 (C1), 129.2-129.4 (Ph groups), 137.1 (C13), 146.4 [C2, 2J(Pt-C)=33Hz], 148.6 (C11), 148.8 (C4); delta(195Pt)-3359. UV-Vis (lambdamax in toluene): 474 and 516nm.
1662-01-7, As the paragraph descriping shows that 1662-01-7 is playing an increasingly important role.
Reference£º
Article; Momeni, Badri Z.; Fathi, Nastaran; Moghadasi, Milad; Biglari, Abbas; Janczak, Jan; Journal of Organometallic Chemistry; vol. 880; (2019); p. 368 – 377;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI