Simple exploration of (1S,2S)-(-)-1,2-Diphenylethylenediamine

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Electric Literature of 29841-69-8, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.29841-69-8, Name is (1S,2S)-(-)-1,2-Diphenylethylenediamine, molecular formula is C14H16N2. In a Article，once mentioned of 29841-69-8

The asymmetric direct vinylogous Michael reaction of alpha,beta- unsaturated gamma-butyrolactams with alkylidene malonates has been developed. Various 5-substituted 3-pyrrolidin-2-ones were obtained in high yields (up to 93%) with excellent stereoselectivities (up to 94% ee, 95:5 dr), using a novel bifunctional C1-symmetric guanidine organocatalyst embodied a secondary amine subunit. The Royal Society of Chemistry 2012.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI