330680-46-1, Trimethyl [2,2′:6′,2”-terpyridine]-4,4′,4”-tricarboxylate is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
1.3g of the compound of the d-1-6 with one equivalent ofCompound d-1-7 NMP (N- methyl pyrrolidone) was stirred for 3 hours in the atmosphere of nitrogen at 70 was added to 150ml. Then compound d-1-8 by the addition of 1 eq., Was stirred at 160 time Heating 8, by the addition of 10 eq of ammonium Ansan between arylthio was stirred at 160 8 hours. After concentration of the resulting solution, by addition of water and filtered. Purification of the filtered water to the silica gel column chromatography, and then the obtained compound d-1-9, was added to a mixed solvent of 30ml of acetone and 40ml 1N sodium hydroxide aqueous solution, was stirred for 24 hours at an external temperature of 65 . It returned to room temperature, adjusted to pH 3 with hydrochloric acid and filtered the precipitate to give 2.5g of crude D-1-5a.
The synthetic route of 330680-46-1 has been constantly updated, and we look forward to future research findings.
Reference£º
Patent; FUJI FILM CORPORATION; WATANABE, KOSUKE; SATO, HIROTAKA; TANI, YUKIO; FUJIWARA, RYO; TSUNA, KAZUHIRO; KOBAYASHI, KATSUMI; (82 pag.)KR2015/129778; (2015); A;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI