Synthetic Route of 65355-00-2, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.65355-00-2, Name is (S)-(-)-5,5,6,6,7,7,8,8-Octahydro-1,1-bi-2-naphthol, molecular formula is C20H22O2. In a Article£¬once mentioned of 65355-00-2
Synthesis, structural analysis, and catalytic properties of tetrakis(binaphthyl or octahydrobinaphthyl phosphate) dirhodium(II,II) complexes
The X-ray structural analyses of homoleptic Rh(II) complexes made of enantiopure (R)-1,1?-binaphthyl and (R)-(5,5?,6,6?,7,7?, 8,8?-octahydro)binaphthyl phosphate ligands are for the first time presented. The possibility to introduce halogen atoms at the 3,3?-positions is also reported. The isolated dirhodium complexes were further tested as catalysts (1 mol %) in enantioselective cyclopropanations and Si-H insertion reactions, affording chiral cyclopropanes and silanes in good yield but moderate enantioselectivity (ee max 63%).
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 65355-00-2
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI