787-70-2, [1,1′-Biphenyl]-4,4′-dicarboxylic acid is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
787-70-2, In a typical preparation, a solid mixture of H2BPDC (H2BPDC = 4,4′-biphenyldicarboxylic acid; 0.1039 g, 0.4 mmol), bpy (bpy = 4,4′-bipyridine; 0.033 g, 0.2 mmol), and Cu(NO3)2¡¤3H2O (0.105 g, 0.4 mmol) was dissolved in a mixture of DMF (DMF = N,N’-dimethylformamide; 30 ml), pyridine (0.3 ml), and methanol (3 ml). The resulting solution was stirred at 70 C for 5 min and then distributed to four 20-ml vials. The vials were then heated at 120 C in an isothermal oven for 24 h. After cooling the vials to room temperature, the solid product was removed by decanting with mother liquor and washed in DMF (3 x 10 ml) for 3 days. Solvent exchange was carried out with methanol (3 x 10 ml) at room temperature for 3 days. The material was then evacuated under vacuum at 140 C for 6 h, yielding 0.103 g of Cu2(BPDC)2(BPY) in the form of blue crystals (67.5% based on copper nitrate).
As the paragraph descriping shows that 787-70-2 is playing an increasingly important role.
Reference£º
Article; Phan, Nam T.S.; Vu, Phuong H.L.; Nguyen, Tung T.; Journal of Catalysis; vol. 306; (2013); p. 38 – 46;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI