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Chemistry is traditionally divided into organic and inorganic chemistry. category: catalyst-ligand. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent£¬Which mentioned a new discovery about 1271-19-8

4-exo cyclizations by template catalysis

Small rings through large templates: A two-point binding of the substrate radicals to cationic titanocene templates is essential for the success of otherwise impossible 4-exo cyclizations (see scheme; Bn=benzyl). The cyclobutanes are obtained in high stereoselectivity and can be additionally functionalized in a straightforward manner.

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Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI