The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: (S)-5-(Hydroxymethyl)dihydrofuran-2(3H)-one, is researched, Molecular C5H8O3, CAS is 32780-06-6, about A ring-expansion route to analogs of dideoxyhydantocidin, the main research direction is dideoxy hydantocidin spirocyclic nucleoside preparation; dihydrofuranyllithium addition azetidinedione; hydroxy lactam acid catalyzed rearrangement.Reference of (S)-5-(Hydroxymethyl)dihydrofuran-2(3H)-one.
The acid-catalyzed rearrangement of hydroxy β-lactam, formed by addition of the enantiopure dihydrofuranyllithium to N-benzyl-2,3-azetidinedione, has been investigated as a potential route to spirocyclic nucleosides.
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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI