The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 344-25-2, Name is H-D-Pro-OH, SMILES is O=C(O)[C@@H]1NCCC1, in an article , author is Rowland, Casey A., once mentioned of 344-25-2, Category: catalyst-ligand.
Novel syntheses of carbazole-3,6-dicarboxylate ligands and their utilization for porous coordination cages
The molecular nature, and thus potential solubility, of coordination cages endows them with a number of advantages as compared to metal-organic frameworks and other extended network solids. However, their lack of three-dimensional connectivity typically limits their thermal stability as inter-cage interactions in these materials are relatively weak. This is particularly the case for carbazole-based coordination cages. Here, we report the design and synthesis of a benzyl-functionalized octahedral coordination cage that displays moderate surface area and increased thermal stability as compared to its unfunctionalized counterpart. Structural analysis suggests the increased thermal stability is a result of aryl-aryl interactions between ligand groups on adjacent cages. We have further adapted the ligand synthesis strategy to afford a novel, high-yielding preparatory route for the isolation of carbazole-3,6-dicarboxylic acid that does not rely on pyrophoric reagents or transition metal catalysts.
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Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI