Synthetic Route of 92149-07-0, Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 92149-07-0, Name is 4,7-Dimethoxy-1,10-phenanthroline, molecular formula is C14H12N2O2. In a Article£¬once mentioned of 92149-07-0
Iron-Catalyzed Reductive Cyclization of o-Nitrostyrenes Using Phenylsilane as the Terminal Reductant
Using microscale high-throughput experimentation, an efficient, earth-abundant iron phenanthroline complex was discovered to catalyze the reductive cyclization of ortho-nitrostyrenes into indoles via nitrosoarene reactive intermediates. This method requires only 1 mol % of Fe(OAc)2 and 1 mol % of 4,7-(MeO)2phen and uses phenylsilane as a convenient terminal reductant. The scope and limitations of the method were illustrated with 21 examples, and an investigation into the kinetics of the reaction revealed first-order behavior in catalyst and silane and zero-order behavior with respect to nitrostyrene.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Synthetic Route of 92149-07-0, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 92149-07-0, in my other articles.
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI