Chemistry is an experimental science, Application In Synthesis of Titanocenedichloride, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 1271-19-8, Name is Titanocenedichloride
The syntheses of several new CpTiCl2(OR) (R = alkyl, aryl) complexes are described.It was possible to isolate pure product when the R group is substituted such as to cause steric crowding at the metal centre; for example, particularly good yields of the phenolate complexes were obtained when there were isopropyl substituents in the 2 and 6 positions of the phenolate.Electrochemical studies of the complexes in dry THF show that the TiIII complexes are relatively stable, but only a diol complex could be reduced further to a TiII species.In general, the TiIV complexes undergo a reversible 1e- reduction reaction.The chemistry is more complex if the electrolyte contains added water: both the TiIV and TiIII complexes can react with water, the OR group being replaced by OH.The reaction is particularly rapid for the TiIII alkoxide complexes. Key words: Titanium; Cyclopentadienyl; Synthesis; Reduction; Electrochemistry
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Application In Synthesis of Titanocenedichloride, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 1271-19-8, in my other articles.
Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI