Application of 16858-01-8, In heterogeneous catalysis, the catalyst is in a different phase from the reactants. At least one of the reactants interacts with the solid surface in a physical process called adsorption in such a way. 16858-01-8, name is Tris(2-pyridylmethyl)amine. In an article，Which mentioned a new discovery about 16858-01-8
The complex ReIII(benzil)(PPh3)Cl3 (2) is used to synthesize a variety of ReIII and ReII polypyridyl complexes of the type cis-[ReIII(L2)2Cl2]+, [ReII(L2)3]2+, ReIII(L3)Cl3, [ReIII(L3)2Cl]2+, and [ReIII(L4)Cl2]+, where L2 = bpy (3 and 6), tbpy (4 and 7), phen (5 and 8); L3 = terpy (9 and 10); L4 = TMPA (11). The complex cis-[ReIII(bpy)2Cl2]+ (3) is a useful synthon in the formation of complexes of the type [Re(bpy)2Lx]n+ that are six- or seven-coordinate ReIII complexes (13, 16, and 18) or octahedral ReII or ReI complexes (12 and 17). The [ReIII(terpy)2Cl]2+ (10) complex can be reduced to form the ReI complex, [ReI(terpy)2]+ (21) and then electrochemically reoxidized to form new complexes of the type [ReIII(terpy)2L]n+. Similar behavior is observed for the [ReII(bpy)3]2+ (6) complex where [ReIII(bpy)3(1BuNC)3+ (20) and [ReI(bpy)3]+ (19) may be formed. The electrochemistry of these complexes is discussed in relation to their reactivity and the observed pi-acidity of the polypyridyl ligands. In addition, X-ray crystal structures for cis-[ReIII(bpy)2Cl2]PF6 (3) and [ReI(bpy)3]PF6 (19) are reported. cis-[ReIII(bpy)2Cl2]PF6 (3, ReC20H16N4Cl2F6P) crystallizes in the monoclinic space group C2/c with Z = 4 and lattice parameters a = 15.043(5) A, b = 13.261(4) A, c = 12.440(4) A, and beta= 108.86(2) at -100 C. [ReI(bpy)3]PF6 (19, ReC30H24N6F6P) crystallizes in the rhombohedral space group R3c(h) (No. 167) with Z = 12 and lattice parameters a = 13.793(3) Aand c = 51.44(3) A at -100 C.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.16858-01-8. In my other articles, you can also check out more blogs about 16858-01-8
Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI