112881-51-3, 4′-(4-Pyridyl)-2,2′:6′,2”-terpyridine is a catalyst-ligand compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
A mixture of NiCl2¡¤6H2O (24mg, 0.10mmol) and pytpy (62mg, 0.20mmol) was dissolved in water (5mL) and then was stirred for 10min in air. The reaction mixture was then transferred into a 23mL Teflon-lined reactor and kept at 200C for 72h and after that it was cooled to room temperature at the rate of 10 Ch-1. The red crystals were obtained after washing with distilled water and drying in air. Yield: 74%; m.p. 344-346C (dec.). Anal. Calc. for C40H28Cl2N8Ni. 4H2O: C, 58.42; H, 4.41; N, 13.63. Found: C, 58.03; H, 4.08; N, 13.77. IR data (KBr, cm-1): 3404, 3015, 2916, 2849, 2352, 1670, 1603, 1537, 1469, 1402, 1249, 1159, 1016, 914, 793, 741, 634, 495. TGA: calc. by formula C40H28N8NiCl2. 1.5H2O: 1.5H2O %=3.48, 2 pyridine and 1 Cl %=25.89, 1Cl %=6.40, 0.5 pyridine %=7.62, 0.5 terpyridine and 0.5 pyridine %=32.57. determined: 1.5H2O %=3.37, 2 pyridine and 1 Cl %=27.18, 1 Cl %=5.35, 0.5 pyridine %=8.94, 0.5 terpyridine and 0.5 pyridine %=35.30.
112881-51-3, 112881-51-3 4′-(4-Pyridyl)-2,2′:6′,2”-terpyridine 11438308, acatalyst-ligand compound, is more and more widely used in various fields.
Reference£º
Article; Momeni, Badri Z.; Rahimi, Farzaneh; Jebraeil, S. Mohammad; Janczak, Jan; Journal of Molecular Structure; vol. 1150; (2017); p. 196 – 205;,
Metal catalyst and ligand design
Ligand Template Strategies for Catalyst Encapsulation – NCBI