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Infinite 1D Ti-O rod-based metal-organic frameworks (MOFs) are promising photocatalysts for water splitting due to their high optical response and favourable photo-redox properties and stability, but have not been explored yet. In this study, three isoreticular porous 1D rod-based Ti-MOFs ZSTU-1, ZSTU-2 and ZSTU-3 are successfully constructed from infinite [Ti6(mu3-O)6(mu2-OH)6]n secondary building units (SBUs) and tritopic carboxylate linkers 4,4?,4??-nitrilotribenzoic acid (H3TCA), 1,3,5-tris(4-carboxyphenyl)benzene (H3BTB) and tris(4?-carboxybiphenyl)amine (H3BTCA), respectively. Their porosities systematically increase with the larger and longer organic linkers. The two MOFs ZSTU-1 and ZSTU-3 built from the triphenylamino-based ligands can absorb visible light, exhibiting much better photocatalytic performance than ZSTU-2 as shown by the H2 production rate of ZSTU-1 and ZSTU-3 being 3-4 times higher than that of ZSTU-2. The photocatalytic H2 production rates for ZSTU-1, ZSTU-2, and ZSTU-3 are 1060 mumol g-1 h-1, 350 mumol g-1 h-1 and 1350 mumol g-1 h-1, respectively. The extraordinary photocatalytic activity of ZSTU-3 is attributed to its visible light absorption, large surface area, and favorable charge separation.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Some scientific research about 5′-(4-Carboxyphenyl)-[1,1′:3′,1”-terphenyl]-4,4”-dicarboxylic acid

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Chemistry is traditionally divided into organic and inorganic chemistry. Formula: C27H18O6. The former is the study of compounds containing at least one carbon-hydrogen bonds.In a patent,Which mentioned a new discovery about 50446-44-1

Stimuli-responsive functional materials with specific properties have been garnering recent attention. Various external stimulations, such as light, mechanical or pressure, vapor, solvent or temperature, have been extensively utilized to induce physical property changes. Temperature, the most fundamental parameter, is believed to serve as an efficient stimulus for triggering luminescence changes. This thermal, stimuli-responsive luminescence change is known as luminescence thermochromism. This review focuses on the systematic developments of metal-containing crystalline luminescence thermochromic materials, which will be of interest to researchers attempting to design and develop new temperature-induced luminescence-changing materials. Additionally, focusing on crystalline materials provides direct insight into the chromic mechanisms of luminescence thermochromism, which are also discussed.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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A series of monophosphite ligands derived from D-fructose and D-glucose have been synthesized and employed in Rh-catalyzed asymmetric hydrogenation of alpha- and beta-dehydroamino acid esters. A variety of chiral alpha- and beta-amino acid esters have been obtained in excellent enantiomeric excess (up to 98.4% ee).

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

The important role of 5′-(4-Carboxyphenyl)-[1,1′:3′,1”-terphenyl]-4,4”-dicarboxylic acid

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This article aims to provide an overview of broad range of applications of synchrotron scattering methods in the investigation of nanoscale materials. These scattering techniques allow the elucidation of the structure and dynamics of nanomaterials from sub-nm to micron size scales and down to sub-millisecond time ranges both in bulk and at interfaces. A major advantage of scattering methods is that they provide the ensemble averaged information under in situ and operando conditions. As a result, they are complementary to various imaging techniques which reveal more local information. Scattering methods are particularly suitable for probing buried structures that are difficult to image. Although, many qualitative features can be directly extracted from scattering data, derivation of detailed structural and dynamical information requires quantitative modeling. The fourth-generation synchrotron sources open new possibilities for investigating these complex systems by exploiting the enhanced brightness and coherence properties of X-rays.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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As a new field in POM-based functional materials, polyoxometalate-based coordination polymers (POMCPs), especially transition-metal-containing POMCPs (TM-POMCPs), have undergone substantial advancements over the past few decades for their impressive structural features and desirable properties in optics, electrochemistry, and organic catalysis. Notably, TM-POMCPs based on Keggin-type POM building blocks have attracted widespread research interest and account for more than half of the compounds reported in this class. Keggin-type POMs, strong Lewis acids with adjustable redox properties, can interact with transition metals via self-assembly in the presence of organic ligands, combining the advantages of the three constituents and resulting in many improved properties. This review focuses on Keggin-type TM-POMCPs, which are extended structures with covalently bound metal-oxide clusters with 1D chains, 2D layers, and 3D frameworks. Such coordination polymers not only enrich the structural diversity of Keggin-type POM derivatives but also provide a suitable pathway for designing functional materials with outstanding properties directed by structure?property relationship. In this review, we highlight and discuss the structural features of Keggin-type TM-POMCPs based on various dimensionalities. Furthermore, synthetic strategies and relevant applications, especially in the field of catalysis, are overviewed.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Purpose: Lymph cancers are heterogeneous malignancies of the hematopoietic and lymphoid tissues. Doxorubicin (DOX) and vincristine (VCR) are commonly used anti-cancer chemotherapeutic drugs, but their clinical uses are associated with dose-limiting systemic toxicity. Methods: In the present study, DOX and VCR were encapsulated into nanostructured lipid carriers (NLCs) and used them to treat B-cell lymphoma cells through the targeted delivery of DOX and VCR to lymph cancer animal model. Results: DOX and VCR encapsulated NLCs (DOX/VCR NLCs) demonstrated controlled drug release under physiological conditions. In addition, DOX/VCR NLCs exhibited the highest cytotoxicity and synergistic effect of two drugs in B-cell lymphoma cells and the best anti-tumor effect in vivo. Conclusion: DOX/VCR NLCs were proved to be more efficacious than the equivalent dose of free DOX and single drug (DOX or VCR) formulation in vitro and in vivo, and significantly reduced the drug-associated systemic toxicity.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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A novel manufacturing process is described for producing quaternary ammonium compounds having a selected anion, which may be useful in wood preservative formulations. The process involves reacting a trialkylamine with an alkyl bromide to form a quaternary tetraalkylammonium bromide salt, converting the quaternary tetraalkylammonium bromide salt to a quaternary tetraalkylammonium hydroxide salt by using an ion exchange resin, and converting the quaternary tetraalkylammonium hydroxide salt to the quaternary tetraalkylammonium salt of the selected anion.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

Extracurricular laboratory:new discovery of 5′-(4-Carboxyphenyl)-[1,1′:3′,1”-terphenyl]-4,4”-dicarboxylic acid

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This review details the emergence and continued study of the template effect in metal-organic frameworks (MOFs)with emphasis upon (i)reports of template-directed synthesis of MOFs and (ii)using MOFs as hosts to template the formation of new guest species. We focus herein on the relationship between the pore environments of MOF hosts and their guests, and the resulting host-guest properties. Such understanding can enable template effects to serve as a supplementary tool of crystal engineering since it can afford new and otherwise unattainable MOF structures. Templating can also result in control over the chemical reactivity of guests through an enzymatic like process. We also address emerging applications of MOFs formed through a template effect. We anticipate that this review will provide a guide for future research into preparing functional MOFs with targeted structures or properties and to generate reaction products using MOFs as templates.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Two coordination polymers of ytterbium were synthesized by employing 4,4?,4?-s-triazine-2,4,6-triyl-tribenzoic acid (H3TATB), 4,4?,4-benzene-1,3,5-triyl-tribenzoic acid (H3BTB), and 3,5-pyridinedicarboxylic acid (3,5-PDC) ligands and were characterized by single-crystal X-ray diffraction analysis. Reaction of ytterbium(III) chloride in the presence of H3BTB and 3,5-PDC ligands gives preferred complexation with the 3,5-PDC ligand, producing [Yb2(3,5-PDC)(ClO4)3][NH(Me)3] (1). However, under exactly the same reaction conditions, reaction of ytterbium(III) chloride in the presence of 3,5-PDC and H3TATB resulted in complexation with H3TATB to form [(CH3)2NH2][Yb4(TATB)4(HCO2)(H2O)2]·3H2O (2). The crystal structure results showed a layered structure for 1 and a metal-organic framework structure for 2. This indicates that the complexation preference of the ytterbium ion is H3TATB ? 3,5-PDC ? H3BTB. Conversely, the uncomplexed ligand in the metal-organic framework (2) is an auxiliary agent during the synthesis, which shows polytopic linker controls crystal properties, to form suitable crystals for single-crystal structure determination. The prepared coordination compounds were used as heterogeneous catalysts in an oxidation amidation reaction with different aldehydes and benzylamine hydrochloride.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI

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Cobalt ferrite (CoFe2O4) nanoparticles (NPs) are synthesized by wet chemical coprecipitation method using metal chlorides as precursors and potassium hydroxide (KOH) as a precipitant. The tergitol-1x (T-1x) and didecyldimethyl ammonium bromide (DDAB) are used as capping agents and their effect is investigated on particle size, size distribution and morphology of cobalt ferrite nanoparticles (CFNPs). The Fourier transform infrared spectroscopy confirms the synthesis of CFNPs and formation of metal-oxygen (M-O) bond. The spinel phase structure, morphology, polydispersity and magnetic properties of ferrite nanoparticles are investigated by x-ray diffraction, scanning electron microscopy, dynamic light scattering and vibrating sample magnetometry analyses, respectively. The addition of capping agents effects the secondary growth of CFNPs and reduces their particle size, as is investigated by dynamic light scattering and atomic force microscopy. The results evidence that the DDAB is more promising surfactant to control the particle size (?13 nm), polydispersity and aggregation of CFNPs. The synthesized CFNPs, CFNPs/T-1x and CFNPs/DDAB are used to study their adsorption potential for removal of acid blue 45 dye, and a maximum adsorptive removal of 92.25% is recorded by 0.1 g of CFNPs/DDAB at pH 2.5 and temperature 20 ± 1 C. The results show that the dye is physically adsorbed by magnetic NPs and follows the Langmuir isotherm model.

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Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI