1119-97-7, Name is MitMAB, belongs to catalyst-ligand compound, is a common compound. 1119-97-7. In an article, authors is Aguas, Ivan, once mentioned the new application about 1119-97-7.
Turpentine valorization by its oxyfunctionalization to nopol through heterogeneous catalysis
Turpentine is a mixture of monoterpene hydrocarbons obtained as a by-product in the paper industry. In this contribution we present its transformation process towards an alcohol named nopol, that is an important household product and fragrance raw material. Reaction conditions were established for the oxyfuntionalization of crude turpentine oil over Sn-MCM-41 catalyst for the selective conversion of beta-pinene to nopol. Synthesized materials were characterized by XRD, N2 adsorption, FT-IR, TEM and chemical absorption. The reaction was tested in 2 mL glass reactor with a sample of commercial turpentine with alpha-pinene (55.5% w/w) and beta-pinene (39.5% w/w) as main components and scaled up into a 100 mL Parr reactor, getting 92% conversion of beta-pinene and a nopol selectivity of 93%. The reusability tests showed that the catalyst can be reused 4 times without loss of activity. The results showed that 86% less solvent and 37.5% less paraformaldehyde can be used with turpentine, compared to the conditions used with beta-pinene for getting similar catalysts activity. Chemical engineering, Organic Chemistry, beta-pinene, turpentine; Nopol; Prins reaction; Sn-MCM-41.
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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI