The Absolute Best Science Experiment for (1S,2S)-(-)-1,2-Diphenylethylenediamine

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Asymmetric aldol reactions employing a cyclic sulfamide chiral auxiliary

A titanium enolate derived from (3S,4S)-2,5-dipropionyl-3,4-diphenyl-1,2,5-thiadiazolidine 1,1-dioxide (3) reacts with aldehydes to give syn aldols with high stereoselection (> 95:5).

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI