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The deuterium isotope effect on the thermodynamic driving force is discussed. Theory correctly predicts a decrease in the kinetic isotope effect as the reaction driving force increases. The observed isotope effect for replacement of H//2O by D//2O is significantly larger than predicted even after correcting for the solvent dependence of the reaction driving force.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. Computed Properties of C16H16N2, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 1660-93-1, in my other articles.
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Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI