128143-89-5, Name is 4′-Chloro-2,2′:6′,2”-terpyridine, molecular formula is C15H10ClN3, belongs to catalyst-ligand compound, is a common compound. In a patnet, author is Jatmika, Catur, once mentioned the new application about 128143-89-5, Quality Control of 4′-Chloro-2,2′:6′,2”-terpyridine.
Ligand Exchange Strategy for Delivery of Ruthenium Complex Unit to Biomolecules Based on Ruthenium-Olefin Specific Interactions
Ligand exchange reactions between a Hoveyda-Grubbs-type complex and 2-alkoxybenzylidene in a biomolecule assist in the delivery of a ruthenium complex unit to the biomolecule. Complexes having an electron-withdrawing group in their ligands efficiently transfer a ruthenium complex unit onto peptides. This method is also applicable for adenylate kinase, an experimental model protein. The ligand exchange reaction originates from ruthenium-olefin specific interactions and potentially provides a bioorthogonal method for chemical modification of biomacromolecules with transition metal complexes.
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Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI