In homogeneous catalysis, the catalyst is in the same phase as the reactant. The number of collisions between reactants and catalyst is at a maximum.In a patent, 1271-19-8, name is Titanocenedichloride, introducing its new discovery. Computed Properties of C10Cl2Ti
Evolved gas analysis of Ti(C5H5)2Cl 2 by means of Li+ ion attachment mass spectrometry
Characterization of the compound Ti(C5H5) 2Cl2 was studied using Li+ ion attachment mass spectrometry (IAMS) as an analytical methodology. Since this target compound is used as an anticancer drug in the treatment of leukemia, accurate and rapid monitoring methods for the determination of titanium drugs in a hospital environment are desirable. A quadrupole mass spectrometry system along with a Li+ ion attachment technique and a direct inlet probe (DIP) produced the Li+ adduct of Ti(C5H5)2Cl 2, Ti(C5H5)2Cl2Li +. The DIP also was used to study the temperature-resolved behavior of this compound. The slope of the plot of signal intensity of Ti(C 5H5)2Cl2Li+ versus temperature for Ti(C5H5)2Cl2 sublimation from 60 to 100 C was used to determine an apparent activation energy (Ea) of 124.43 kJ/mol for the sublimation of Ti(C 5H5)2Cl2. This value is comparable to the reported value of 118.8 kJ/mol for molar enthalpy of sublimation of Ti(C5H5)2Cl2. These results demonstrate that the IAMS methodology can be used to study the enthalpy of sublimation for d-metal complex materials.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 1271-19-8 is helpful to your research. Computed Properties of C10Cl2Ti
Reference£º
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI