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Lanthanides and group III metal triflates (especially La, Sm) accelerate the Baylis-Hillman reaction (reaction between an unsaturated ester and aldehyde catalysed by DABCO, for example) and further acceleration can be obtained upon addition of diol ligands such as binol.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI