Let¡¯s face it, organic chemistry can seem difficult to learn, COA of Formula: C5H10N2O, Especially from a beginner¡¯s point of view. Like 7531-52-4, Name is H-Pro-NH2, molecular formula is catalyst-ligand, belongs to catalyst-ligand compound. In a document, author is Mostakim, S. K., introducing its new discovery.
An Anthracene-Based Metal-Organic Framework for Selective Photo-Reduction of Carbon Dioxide to Formic Acid Coupled with Water Oxidation
A Zr-based metal-organic framework has been synthesized and employed as a catalyst for photochemical carbon dioxide reduction coupled with water oxidation. The catalyst shows significant carbon dioxide reduction property with concomitant water oxidation. The catalyst has broad visible light as well as UV light absorption property, which is further confirmed from electronic absorption spectroscopy. Formic acid was the only reduced product from carbon dioxide with a turn-over frequency (TOF) of 0.69 h(-1) in addition to oxygen, which was produced with a TOF of 0.54 h(-1). No external photosensitizer is used and the ligand itself acts as the light harvester. The efficient and selective photochemical carbon dioxide reduction to formic acid with concomitant water oxidation using Zr-based MOF as catalyst is thus demonstrated here.
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Reference:
Metal catalyst and ligand design,
,Ligand Template Strategies for Catalyst Encapsulation – NCBI