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Phosphoroselenoyl chloride bearing a l,1?-bi-2-naphthyl group was reacted with racemic 2-alkanols to give the corresponding esters. Based on the multiple combination of their NMR spectra, a method for the assignment of the absolute configuration of 1 -aryl-2-propanols was established. The solidstate conformations of the esters were confirmed by X-ray structure analyses.

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Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI