A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, Product Details of 162318-34-5, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 162318-34-5, Name is 5-Ethynyl-2,2′-bipyridine, molecular formula is C12H8N2. In a Article, authors is Zhang, Yuzhen，once mentioned of 162318-34-5
Coordination-driven self-assembly delivers discrete, nanoscopic architectures that may preserve or enhance the physicochemical properties of their parent building blocks. Herein, we report the syntheses, characterization, and photophysical properties of two tetrahedral cages, [ZnII4L6](PF6)8 (C1) and [FeII4L6](OTf)8 (C2), where L = PtII(PEt3)2(C?C-bpy)2 (PEt3 = triethylphosphine; C?C-bpy = 5-ethynyl-2,2?-bipyridine) and OTf = trifluoromethanesulfonate. C1 and C2 were assembled in isolated yields of 72% and 81% by treating 2 equiv of Zn(NO3)2·6H2O or Fe(OTf)2 with 3 equiv of L, respectively. Both cages were fully characterized by NMR, electrospray ionization mass spectrometry, and single-crystal X-ray diffraction (SCXRD). The local D3 symmetry at each polypyridyl metal node raises the possibility of a number of isomeric cages; however, only the homochiral enantiomers (DeltaDeltaDeltaDelta and lambda lambda lambda lambda) are formed based on 1H NMR and SCXRD. C1 exhibits phosphorescence centered at 545 nm with a quantum yield of 10% in N2-degassed acetonitrile at 25 C. The quantum yield of C2 is significantly lower due to a nonradiative relaxation from 5MC (MC = metal-centered) states introduced by the FeII nodes.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 162318-34-5, help many people in the next few years.Product Details of 162318-34-5
Reference：
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI