Product Details of 89972-77-0. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: 4-(p-Tolyl)-2,2:6,2-terpyridine, is researched, Molecular C22H17N3, CAS is 89972-77-0, about Structural consequences of the steric effects of the organoimine ligand in the oxovanadium-organophosphonate/copper-mephenterpy family of hybrid oxides (mephenterpy = 4′-(4-methyphenyl)-2,2′:6′,2”-terpyridine). Author is Yucesan, Gundog; Yu, Min Hui; O’Connor, Charles J.; Zubieta, Jon.
Hydrothermal reactions of CuSO4·5H2O, Na3VO4, 4′-(4-methylphenyl)-2,2′:6′,2”-terpyridine (mephenterpy) and the appropriate diphosphonic acid provided materials of the Cu(II)-mephenterpy/oxovanadium organophosphonate family. Four 1-dimensional compounds were isolated: [{Cu(mephenterpy)}(VO2)(HO3PCH2PO3)] (1), [{Cu(mephenterpy)}2(V3O6)(O3PCH2CH2PO3)(HO3PCH2CH2PO3)] (2), [{Cu(mephenterpy)}(VO2)(HO3PCH2CH2CH2PO3)] (3) and [{Cu(mephenterpy)}2(V2O5)2(O3PCH2CH2CH2PO3)] (4). Although all share a common dimensionality, the detailed connectivities within the chains result in four distinct vanadophosphonate substructures: {(VO2)(HO3PCH2CH2PO3)}n2n- chains in 1, {(V3O6)(O3PCH2CH2PO3)(HO3PCH2CH2PO3)}n4n- chains in 2, [(VO2)2{HO3P(CH2)3PO3}2]4- rings in 3 and [(V2O5)2{O3P(CH2)3PO3}]n4n- chains in 4. When the diphosphonate tether is a butylene group, the copper phase [Cu(mephenterpy){HO3P(CH2)4PO3H}]·H2O (5) is isolated. 1-5 Were characterized by x-ray crystallog.
This compound(4-(p-Tolyl)-2,2:6,2-terpyridine)Product Details of 89972-77-0 was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
Reference:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI