In 2019,Organic Chemistry Frontiers included an article by Zhou, Qing; Chen, Bo; Huang, Xiao-Bing; Zeng, Ya-Li; Chu, Wen-Dao; He, Long; Liu, Quan-Zhong. Synthetic Route of C51H42O3Pd2. The article was titled 《Palladium-catalyzed diastereo- and enantioselective formal [3+2] cycloaddition of vinyl cyclopropanes with cyclic 1-azadienes》. The information in the text is summarized as follows:
Palladium-catalyzed asym. formal [3+2] cycloadditions of vinyl cyclopropanes and cyclic 1-azadienes proceeded smoothly in the presence of chiral phosphoramidite ligands to afford the corresponding highly functionalized cyclopentanes in good yields along with high enantioselectivities under mild conditions. The experimental process involved the reaction of Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3Synthetic Route of C51H42O3Pd2)
Tris(dibenzylideneacetone)dipalladium(0)(cas: 51364-51-3) is the most widely used PdO precursor complex in synthesis and catalysis, in particular as a catalyst for various coupling reactions. Synthetic Route of C51H42O3Pd2 It also used for palladium-catalyzed one-pot synthesis of tricyclic indolines, in the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles and cross-coupling of aryl halides with aryl boronic acids.
Referemce:
Metal catalyst and ligand design,
Ligand Template Strategies for Catalyst Encapsulation – NCBI